catena-Poly[[[diaquabis(2-methyl-6-oxo-1,6-dihydro-3,4′-bipyridine-5-carbonitrile)copper(II)]-μ-sulfato] tetrahydrate]
نویسندگان
چکیده
In the title polymer, {[Cu(SO(4))(C(12)H(9)N(3)O)(2)(H(2)O)(2)]·4H(2)O}(n), both the metal center and the sulfate anion are located on a twofold axis. The Cu(II) ion is coordinated by two pyridyl N atoms from two symmetry-related organic ligands, two O atoms from two symmetry-related water mol-ecules, and two O atoms from two symmetry-related sulfate anions, resulting in a distorted octa-hedral geometry. The sulfate anions act as μ(2)-bridges and connect metal ions, forming a one-dimensional chain along the b axis. The three-dimensional crystal structure is established through inter-molecular N-H⋯O and O-H⋯O hydrogen bonds involving the organic ligands, sulfate anions, coordinated and uncoordinated water mol-ecules, and through π-π inter-acting 2-pyridone rings, with centroid-centroid separations of ca 3.96 Å and tilt angles of ca 2.62°.
منابع مشابه
catena-Poly[[[diaquabis(1H-indole-3-acetato-κO)cobalt(II)]-μ-4,4′-bipyridine-κ2 N:N′] tetrahydrate]
The 4,4'-bipyridine spacer in the title compound, [Co(C(10)H(8)NO(2))(2)(C(10)H(8)N(2))(H(2)O)(2)]·4H(2)O, links the diaqua-cobalt(II) dicarboxyl-ate units into a linear chain; the metal atom lies on a center of inversion in an octa-hedral environment. The coordinated and uncoordinated water mol-ecules inter-act through O-H⋯O hydrogen bonds to form a three-dimensional network.
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